Korean Institute of Surface Engineering

pISSN : 1225-8024 | eISSN : 3399-8403


공학

한국표면공학회지 (34권1호 17-24)

Zricaloy-4 Oxidation Kinetics in High-Pressure High-Temperature Steam

지르칼로이-4의 고압 고온 수증기에서 산화 반응 속도

박광헌;김규태;

경희대학교 원자력공학과;한전 원전연료주식회사;

Abstract

A model for quantifying the effect of steam pressure on the oxide thickness growth was developed based on the experimental data available. First, empirical equations for the thickness estimation of oxide formed in 1 atm steam were made. The oxide growth kinetics turned out to be dependent on 0.4th power of oxidation time. With an assumption that the transition oxide thickness be only a function of temperature, a model for the enhancement of steam pressure on oxide growth was developed. The enhancement coefficient for steam pressure is calculated to be 0.01~0.013 $bar^{-}$. The developed model generally well explains the experimental data.a.

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