Korean Institute of Surface Engineering

pISSN : 1225-8024 | eISSN : 3399-8403


공학

한국표면공학회지 (30권3호 183-190)

Crystallization of Yttria-Stabilized-Zirconia Film by Sol-Gel Process

졸-겔법에 의한 이트리안 안정화 지프코니아박막의 결정화

서원찬;조차제;윤영섭;황운석;

인하대학교 금속공학과;

Abstract

Fabrication and crystallization characteristics of yttria($T_2O_3$) stabilized zirconia(YSZ) thin film by sol-gel process were studied. YSZ sol was synthesized with zirconium n-propoxide($Zr(OC_3H_7)_4)$) and yttrium nitrate pentahydrate ($Y(NO_3)_3.5H_2O$). YSZ film was prepared by depositing the polymeric sol on porous $Al_2O_3$ substrate by spin-coating, and the film characteristics were investigated by FRIR, TG-DTA, XRD, DSC, optical microscopy and SEM. The film topology was uniform and cracks were not found. It was found that the annealing temperature and the concentration of stabilizer affect the crystallization of YSZ film. The YSZ film began to crystallize from amorphous to tetragonal phase at 40$0^{circ}C$, and it was not converted to cubic structure until $1100^{circ}C$. It seemed that the grains were formed over $700^{circ}C$and the average grain size was obtained about 0.2$mu extrm{m}$.

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