Korean Institute of Surface Engineering

pISSN : 1225-8024 | eISSN : 3399-8403


공학

한국표면공학회지 (28권6호 333-342)

A study on the formation of oxide scale on the stainless steel to improve the oxidation resistance

스테인레스강의 내산화성 향상을 위한 스케일 형성에 관한 연구

김대환;김재철;김길무;

충남대학교 재료공학과;한국전력기술연구원;

Abstract

Stainless steels are widely selected as commercial engineering materials mainly because of their excellent corrosion resistance, oxidation resistance and strength. Because the manufacturing temperature of stainless steels is relatively high, the chemical and physical properties of the oxide film which was formed on the stainless steels are of importance in determining the rate of oxidation and the life of equipment exposed to high temperature oxidizing environments. In this study, the oxidation behavior of S. S. 304 and S. S. 430 added by a small amount of oxygen active elements(each +0.5wt% Hf and Y) was studied to improve oxidation resistance. The results of cyclic and isothermal oxidation on S. S. 304 added by OAE showed relatively poor oxidation resistance due to spallations and cracks of $Cr_2O_3$ layer. But all S. S. 430+0.5wt% OAE maintained constant oxidation rates and stable oxide layers at high temperature environment. Especially S. S. 430+0.5wt% Y formed a $Cr_2O_3$ oxide layer and improved cyclic oxidation resistance preventing loss of protective layers about 1000 hours at $1000^{circ}C$

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