Korean Institute of Surface Engineering

pISSN : 1225-8024 | eISSN : 3399-8403


공학

한국표면공학회지 (26권5호 255-262)

MICRSTRUCTURAL INVESTIGATION OF CALCINED AND SULFATED LIMESTONE FOR THE UTILIZAION IN THE AFBC ENVIRONMENT


Kim, Hyung-Taek;Kim, Dong-Hyung;Kim, Hong-Tae;Hyukbo Kwon;


Ajou University;Dept. of Solar Thermal Energy;Kyungbuk National University;Kyungnam University;

Abstract

Major parameters determining the extent of Ca utilization were investigated for their calcination/sulfation behavior of limestone in the AFBC(Atmospheric Fluidized Bed Combustion) environments. Three different particle sizes of Fredonia limestone were investigated in the lab-scale tubular reactor. The results of the calcination codnversion of limestone imply that thesd decomposition rate of CaCO3 into CaO is dependent on the amount of heat which limestone absorbed. Hg porosimeter measurement of calcined limestone illustrated that surface area and pore volume are increased with decreasing particle size. Raw Fredonia limestone and sequentially as well as simultaneously calcined/sulfated limestones were also examined using SEM. The SEM Studied showed that the surface of the calcined limestone particles is more diffusive nature than that of the parent calcite. However, the sulfur distribution pattern of simultaneously-treated particles and that of the se-quentially-treated one shows no difference.

Keywords