한국표면공학회지 (23권1호 27-33)
A Thermodynamic Analysis on Silicon Consumption during The Chemical Vapper Deposition of Tungsten
텅스텐의 화학증착시 Si소모에 관한 열역학적 분석
정태희;이정중;
서울대학교 공과대학 금속공학과;
Thermodynamic analysis on silicon consumpton during the chemical vapor deposition of tungten was carried out by calculation equilibrium concerations of all possible product species utilizing a computer progrom according to VCS.(Villars-Cruise-Smith) algorithm. The calculation could show various reaction paths which dominate the tungsten deposition under different process conditions. According to the calculation, the consumption of silicon can also be reduced at a lower total pressure SiH4 without H2 as the reacting gas is most effective for suppression of the excessive consumption of silicon during the deposition process.