Korean Institute of Surface Engineering

pISSN : 1225-8024 | eISSN : 3399-8403


공학

한국표면공학회지 (18권2호 53-60)

Microstructure of zinc electrodeposits in acid sulfate solution

黃酸亞鉛 電解液을 使用한 亞鉛電着層의 顯微鏡 組織

예길촌;안덕수;김용웅;
Ye, Gil-Chon;An, Deok-Su;Kim, Yong-Ung;

영남대학교 금속공학과;포항제철연구소;
Dept. of Metallurgical Engineering Yeungnam University;Pohang Iron & Steel Co., Ltd.;

Abstract

The microstructure of zine electrodeposits was investigated by using zinc sulfate solution in still bath. The cathode current efficiency decreased with increasing current density, and decreasing temperature. The preferred orientation of the zinc electrodeposits changed from (10.3) texture to(10.${ell}$)-(00.1)(${ell}$=1, 2, 3) texture through (10.2)-(10.3) preferred orientation with increasing cathode over potential. The surface morphology of zinc electrodeposits changed from the dendritic growth with granular crystallites to the blocks of hexagonal crystallites packed together with increasing current density. The microstructure of cross section of the above deposits are the rough granular structure and columnar structure respectively.

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