Korean Institute of Surface Engineering

pISSN : 1225-8024 | eISSN : 3399-8403


공학

한국표면공학회지 (52권4호 227-232)

Effects of Cu Addition on Microstructural and Mechanical Properties of Mo-Cu-N Coatings

Cu 첨가가 Mo-Cu-N 코팅의 미세구조와 기계적 특성에 미치는 영향

김수빈;윤혜원;이한찬;문경일;홍현선;
Kim, Soobyn;Yoon, Hae-Won;Lee, Han-Chan;Moon, KyoungIl;Hong, Hyun Seon;

성신여자대학교 청정융합과학과;한국생산기술연구원 열처리그룹;
Department of Interdisciplinary Eco Science, Sungshin University;Heat Treatment R&D Group, Korea Institute of Industrial Technology;

DOI : 10.5695/JKISE.2019.52.4.227

Abstract

Mo-N based coatings have been studied for enhancing mechanical characteristics of thin films. In the case of Mo-X-N coatings, the microstructure and mechanical properties can be affected by the addition of the third element. In this work, Mo-Cu-N coatings were successfully fabricated with varying the Cu content from 4.5 at% to 31 at% by the co-sputtering method. Thus, properties of the coatings were analyzed by EDS, SEM, XRD, AFM, nano indentation and scratch test techniques. From observed results, MoxN bonds were made in a nitrogen atmosphere and Cu elements were present at grain boundaries. In addition, coatings with the Cu content above 14 at% had a Cu3N peak in the XRD results. Thus, it is suggested that the formation of Cu3N phase affected the microstructure and mechanical properties of Mo-Cu-N coatings. Mechanical properties of Mo-Cu-N coatings were found to be relatively better at Cu content of about 12 at%.

Keywords

Mo-Cu-N;Cu content;Sputtering;Nanocomposite coating;Thin film;