Korean Institute of Surface Engineering

pISSN : 1225-8024 | eISSN : 3399-8403


공학

한국표면공학회지 (50권4호 251-258)

Corrosion Damage Characteristics of STS 304 for the Nuclear Power Plant with Chemical Decontamination Conditions in Permanganic and Oxalic Acid

과망간산과 옥살산 화학제염 공정 시 원전기기용 STS 304 의 부식 손상 특성

한민수;정광후;양예진;박일초;김기철;서범철;박주현;김성종;
Han, Min-Su;Jung, Kwang-Hu;Yang, Ye-Jin;Park, Il-Cho;Kim, Ki-Chul;Seo, Bum-Chul;Park, Ju-Hyun;Kim, Seong-Jong;

목포해양대학교 기관시스템공학부;한전KPS;
Division of Marine Engineering, Mokpo National Maritime University;KEPCO Plant Service&Engineering Co., LTD;

DOI : 10.5695/JKISE.2017.50.4.251

Abstract

This study was carried out with solution temperature variables of $75^{circ}C$ and $90^{circ}C$ for STS 304, which is a nuclear equipment material, in order to determine the corrosion damage behavior in chemical decontamination process using permanganic acid and oxalic acid. Then electrochemical polarization experiment, weight loss measurement, surface morphology observation and surface damage depth were measured every cycle of the decontamination process to analyze the degree of corrosion damage. As a result, the corrosion current density, weight loss, and surface damage increased as the decontamination process cycle increased, and the corrosion damage of STS 304 tended to increase. Few ${mu}m$ pitting damage was observed on the surface observation. In 5 cycle, the elongated wormhole-type pitting damage appeared, leading to relatively large surface damage. However, there was no significant difference in the degree of surface damage resulting from the increase in the temperature of the chemical decontamination solution.

Keywords

Permanganic acid;Oxalic acid;Chemical decontamination;STS 304;Corrosion damage behavior;