Korean Institute of Surface Engineering

pISSN : 1225-8024 | eISSN : 3399-8403


공학

한국표면공학회지 (43권4호 205-210)

Analysis on the Scales formed on the Heat Affected Zone of Low Carbon Steel Weld in NaCl and H2S Water Solutions

저탄소강 용접열영향부의 NaCl, H2S 수용액에서 생성되는 부식스케일 분석

김민정;배동호;이동복;
Kim, Min-Jung;Bae, Dong-Ho;Lee, Dong-Bok;

성균관대학교 신소재공학과;성균관대학교 기계공학과;
School of Advanced Materials Science & Engineering, Sungkyunkwan University;School of Mechanical Engineering, Sungkyunkwan University;

DOI : 10.5695/JKISE.2010.43.4.205

Abstract

The A106 Gr B low carbon steel, which was used in the electric power plants and heavy chemical plants, was welded by multi-pass arc welding. The heat affected zone (HAZ) formed by welding was corroded in acid chloride solution, or in saturated $H_2S$ containing acid chloride solution, or in saturated $H_2S$ containing acid chloride solution under applied current. In this order of corrosion solution, the rate of corrosion increased, because $H_2S$ accelerated the iron dissolution, hydrogen evolution, and the formation of nonprotective FeS, whereas the applied current accelerated the electrochemical reaction. The scales formed in acid chloride solution consisted primarily of $Fe_3O_4$, while those formed in $H_2S$ containing acid chloride solution consisted primarily of $Fe_3O_4$ and FeS.

Keywords

A106 Gr B steel;Weld;Corrosion;NaCl;$H_2S$;Heat affected zone;