공학
한국표면공학회지 (43권1호 36-40)
Characterization of Air and SO2 Gas Corrosion of Silicon Carbide Nanofibers
탄화규소 나노섬유의 고온 대기 및 SO2 가스분위기에서의 부식물성
김민정;이동복;
Kim, Min-Jung;Lee, Dong-Bok;
성균관대학교 신소재공학과;
School of Advanced Materials Science & Engineering, Sungkyunkwan University;
DOI : 10.5695/JKISE.2010.43.1.036
Abstract
The SiO vapor that was generated from a mixture of Si and $SiO_2$ was reacted at $1350^{circ}C$ for 2 h under vacuum with carbon nanofibers to produce SiC nanofibers having an average diameter of 100~200 nm. In order to understand the gas corrosion behavior, SiC nanofibers were exposed to air up to $1000^{circ}C$. SiC oxidized to amorphous $SiO_2$, but its oxidation resistance was inferior unlike bulk SiC, because of high surface area of nanofibers. When SiC nanofibers were exposed to Ar-1% $SO_2$ atmosphere, SiC oxidized to amorphous $SiO_2$, without forming $SiS_2$, owing to the thermodynamic stability of $SiO_2$.
Keywords
Carbon nanofiber;Silicon carbide;Air-oxidation;$SO_2$ gas corrosion;