Photolytic Characteristics of Ni-TiO2 Composite Coating from Electroless Plating
무전해 Ni-TiO2 복합도금을 이용한 광분해 특성 연구
최철영;한길수;조일국;김영석;김양도;
Choi, Chul-Young;Han, Gil-Soo;Jo, Il-Guk;Kim, Young-Seok;Kim, Yang-Do;
부산대학교 재료공학부;한국생산기술연구원 동남권기술지원본부;
School of Materials Science and Engineering, Pusan National University;Division of Dongnam Area Technology Service, Korea Institute of Industrial Technology;
DOI : 10.5695/JKISE.2009.42.4.157
Many fundamental studies have been carried out regarding waste water and hazardous gas treatments technologies using the photolysis effect of $TiO_2$. However, a permanent use of $TiO_2$ particles immobilized using organic or organic-inorganic binders is impossible. In this study, Ni-$TiO_2$ composite coating was produced by electroless plating to trap $TiO_2$ particles in the Ni coating layer. The electroless plating was performed in the bath solutions with three different concentrations of $TiO_2$ particles : 10 g/l, 20 g/l, and 40 g/l. The surface and photolytic characteristics of the coating layer was investigated by the use of SEM, a scratch tester, and an UV-Visible spectrophotometer. The results showed that the amounts of immobilized $TiO_2$ particles and the photolytic rate of the coating increased with the initial content of $TiO_2$ particles in the electroless bath. In addition, the photolytic rate of the Ni-$TiO_2$ composite coating was remarkably promoted by etching process in 10% HCl solution.