한국표면공학회지 (12권3호 167-173)
The mechanism of the formation of an anodic oxide layer on the aluminium
알루미늄 양극산화피막의 생성기구
박순;강탁;
Park, Soon;Kang, Tak;
서울대학교 대학원 금속공학과;서울대학교 공과대학 금속공학과;
The structure of anodic aluminium oxide films formed in 2% oxalic asid at constant temperature was studied by the oid of the transmission and replica electron microscopy. Far the initial stage of oxidations, it is observed that pores are initiated from lattice defects as subgrain boundaries, and then spread radially. Some pores merge each other and the others cease to grow until the current density reaches to the steady state. The pore diameter and the cell size are proportional to the anodizing voltages, and it is considered that the pore initiation and growth are largely controlled by the field - assisted oxide dissolution.