Korean Institute of Surface Engineering

pISSN : 1225-8024 | eISSN : 3399-8403


공학

한국표면공학회지 (42권1호 47-52)

Preparation of Cu-Ag Powder having Core-Shell Structure by Electroless Plating Method

무전해 도금법을 이용한 코어 셸 구조의 Cu-Ag분말 제조

김종완;이혁희;원창환;
Kim, Jong-Wan;Lee, Huk-Hee;Won, Chang-Whan;

충남대학교 급속응고신소재연구소;한국화학연구원;
Engineering Research Center for Rapidly Solidified Materials, Chungnam National University;Korea Research Institute of Chemical Technology;

DOI : 10.5695/JKISE.2009.42.1.047

Abstract

Cu-Ag powder having Core-Shell structure was prepared from by electroless plating method using agents such as $AgNO_3$, $NH_{4}OH$, Hydroquinone. Ag coated copper powders were analyzed using scanning electron microscopy(SEM) and energy dispersive X-ray spectrometer(EDX). The silver coating layer of copper powder was affected from various reaction conditions such as molar ratio of $NH_{4}OH$, $AgNO_3$, and pulp density. Free silver was generated below 0.1M or 0.3M and above of $NH_{4}OH$ mole ratio. Silver coating layer thickened as addition of $AgNO_3$. When the pulp density reached 12% with 0.2M $NH_{4}OH$, and 0.15M $AgNO_3$ at $4^{circ}C$, silver was homogeneously distributed around the copper particles and free silver particles were not generated.

Keywords

Silver;Copper;Electroless plating;Reduction;Core-shell;