Korean Institute of Surface Engineering

pISSN : 1225-8024 | eISSN : 3399-8403


공학

한국표면공학회지 (41권5호 240-244)

Surface and Photolytic Characteristics of Ni-TiO2 Composite Layer Electro-Plated from Non-Aqueous Electrolyte

비수용액 전해질에서 전기도금한 니켈-TiO2 복합 도금층의 표면 및 광분해 특성 연구

조일국;지창욱;최철영;김영석;김양도;
Jo, Il-Guk;Ji, Chang-Wook;Choi, Chul-Young;Kim, Young-Seok;Kim, Yang-Do;

부산대학교 재료공학부;한국생산기술연구원 동남권기술지원본부 수송기계부품지원센터;
School of Materials Science and Engineering, Pusan National University;Division for Dongnam Area Technology Service, Korea Institude of Industrial Techology;

DOI : 10.5695/JKISE.2008.41.5.240

Abstract

Composite plating is a method of co-deposition of plating layer with metallic and/or non-metallic particles to improve the plating layer properties such as high corrosion resistance and photolysis of organic compounds. The properties of nickel-ceramic composite plating are significantly depend on the surface characteristics of co-deposited particles as well as the quantity in electrolyte. In this study, Ni-$TiO_2$ composite coating layer was produced by electrodeposition technique from non-aqueous eletrolyte and its surface characteristics as well as photolytic properties were investigated. The amounts of immobilized $TiO_2$ particles increased with increasing the initial $TiO_2$ particles contents in the bath. Samples electroplated with the current density of $0.5;A/dm^2$ showed the significantly improved homogeneous $TiO_2$ particles distribution. The corrosion resistance of Ni-$TiO_2$ composite coating layer also improved with increaing the amounts of $TiO_2$ particles. Etched sample showed about 10% increased photolytic rate of organic matter compare to that of the non-etched.

Keywords

$TiO_2$;Non-aqueous plating;Photolysis;Ethanol;