Korean Institute of Surface Engineering

pISSN : 1225-8024 | eISSN : 3399-8403


공학

한국표면공학회지 (41권3호 114-120)

Surface Properties of the High Porous Carbon Aerogels

고다공성 카본 에어로젤(C-Aerogel) 표면 특성

김지혜;이창래;정용수;김양도;김인배;
Kim, Ji-Hye;Lee, Chang-Rae;Jeong, Young-Soo;Kim, Yang-Do;Kim, In-Bae;

재료연구소 표면기술연구부 연료전지소재연구그룹;부산대학교 공과대학 재료공학과;
Korea Institute of Materials Science (KIMS), Dept. Surface Technology;Pusan National University, School of Materials Science & Engineering;

DOI : 10.5695/JKISE.2008.41.3.114

Abstract

The pyrolysized carbon xerogel and aerogels were prepared from the sol-gel polymerization of resorcinol-formaldehyde(RF) followed by the dry process under ambient pressure and supercritical carbon dioxide condition respectively. The thermal behaviour of RF polymer xerogel was investigated with TGA analyzer to correspond with the pyrolysis process. The surface properties such as particle size, morphology and the point of zero charge of the pyrolysized porous carbon aerogels were studied for the precious metal catalyst supported media. It was found that the volume of the polymer aerogel decreased because of the significant linear shrinkage and weight loss of polymer gel during the carbonization. The point of zero charge of the carbon aerogel pyrolysized at $1050^{circ}C$ under inert gas flow was about 10.

Keywords

Carbon aerogel;Porous materials;Catalyst supported media;Point of zero charge (PZC);