공학
한국표면공학회지 (36권6호 461-465)
A Study of Structures and Magnetic Properties of Electrodeposited Fe-45 wt%Ni-P Alloys
전착법에 의한 Fe-45 wt%Ni-P 합금의 조직과 자기적 성질에 관한 연구
구승현;이흥렬;김동환;황태진;임태홍;
한국생산기술연구원 나노표면기술팀;고려대학교 재료공학부;
Abstract
The microstructures and magnetic properties of electrodeposited Fe-45 wt%Ni-P alloys have been investigated. The structures of electrodeposited Fe-45 wt%Ni alloy was FCC i.e. ${gamma}$ phase and the size of crystallite was 10 nm. The structure of electrodeposited Fe-45 wt%Ni-1 wt%P alloy showed ${gamma}$ phase and 7 nm sized nanocrystalline. The electrodeposited Fe-45 wt%Ni-P alloys containing 2∼3 wt% of P exhibited ${gamma}$ + $alpha$ dual phases. The electrodeposited Fe-45 wt%Ni-P alloys above 3.5 wt% showed an amorphous structure. P in the alloys acted grain refining and phase changing element. The resistivity of the electrodeposited alloys increased with P contents. Effective permeability at high frequency (above 1 MHz) increased with P contents up to 2 wt% and this was ascribed to the easier magnetization rotation owing to the reduction of eddy current. Effective permeability decreased with P contents above 3 wt% and this was ascribed to the transformation of the ferromagnetism of Fe-45 wt%Ni alloy gradually into paramagnetism with the introduction of P into the electrodeposited alloy matrix.
Keywords
Fe-Ni-P alloys;Electrodeposition;Nanocrystalline;Permeability;